My diet:
Comparison

Potassium Sorbate vs Sodium Benzoate

The short answer
Potassium sorbate is the milder choice: it has a higher safe daily limit and no benzene issue. Sodium benzoate works best in very acidic drinks and sauces, but with vitamin C it can form traces of benzene.
Side by sidePotassium SorbateSodium Benzoate
Safety score86/100 Generally safe62/100 Use in moderation
Best forCheese, wine, baked goods, dried fruitSoda, pickles, sauces, juices
StopsMostly molds and yeastsYeasts and some bacteria
Works up toAbout pH 6.5 ✓ BetterAbout pH 4.5 (acidic foods only)
Benzene risk with vitamin CNone ✓ BetterSmall, under limits in most drinks
Safe daily limit (EFSA)11 mg per kg ✓ Better5 mg per kg
Safety score86 ✓ Better62

Swapping one for the other

Many drink makers now pair potassium sorbate with citric acid instead of using sodium benzoate. When shopping, products with neither are usually refrigerated or pasteurized.

Common questions

Why do some drinks contain both?

Together they cover more microbes at lower doses of each, so makers often use a little of both.